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In spite of its dependence on temperature, K is called the equilibrium constant for the reaction; vi Gp, represented by AGO, is called the standard Gibbs-energy change of reaction The fugacity ratios in Eq (1310) provide the connection between the equilibrium state of interest and the standard states of the individual species, for which data are presumed available, as discussed in Sec 135 The standard states are arbitrary, but must always be at the equilibrium temperature T The standard states selected need not be the same for all species taking part in a reaction However, for aparticular species the standard state represented by G must be the P same state as for the fugacity f," The function AGO = viGP in Eq (1312) is the difference between the Gibbs energies of the products and reactants (weighted by their stoichiometric coefficients) when each is in its standard state as a pure substance at the standard-state pressure, but at the system temperature Thus the value of AGO is fixed for a given reaction once the temperature is established, and is independent of the equilibrium pressure and composition Other standard property changes of reaction are similarly defined Thus, for the general property M:

If you had errors during the process of patching the kernel, don t despair This probably means one of two things: The patch version number cannot be applied to the kernel version number (for instance, you tried to apply patch-2650bz2 to Linux-2660) The kernel source itself has changed (This happens to developers who forget that they made changes!)

In accord with this, A H 0 is defined by Eq (414) and AC; by Eq (416) These quantities are functions of temperature only for a given reaction, and are related to one another by equations analogous to property relations for pure species For example, the relation between the standard heat of reaction and the standard Gibbsenergy change of reaction may be developed from Eq (639) written for species i in its standard state:

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motors are spinning with the same duration, such as 300 degrees or 2.5 rotations. This behavior is one of the advantages of the NXT motors. Take a look at the following pseudo-code: Me: SPOT, move forward 360 degrees and wait 3 seconds. Me: Now, move forward 270 degrees and wait 3 seconds. Me: Now, move forward 90 degrees and stop. The NXT-G program for this pseudo-code looks like the one shown in Figure 24-2.

Total derivatives are appropriate here because the properties in the standard state are functions of temperature only Multiplication of both sides of this equation by vi and summation over all species gives:

The easiest way to fix either situation is to erase the kernel located in the directory where you unpacked it and then unpack the full kernel there again This will ensure that you have a pristine kernel Then apply the patch It s tedious, but if you ve done it once, it s easier and faster the second time Finally, a vanilla kernel source tree contains great documentation about kernel patching The file is usually found here: <kernel-source>/ Documentation/applying-patchestxt

In view of the definitions of Eqs (414) and (1312), this may be written:

9:

Since the standard-state temperature is that of the equilibrium mixture, the standard property changes of reaction, such as AGO and A H , vary with the equilibrium temperature The

TIP You can usually back out of (remove) any patch that you apply by using the -R option with the patch command For example, to back out of a patch version 2660 that was applied to Linux kernel version 2659, while in the root of the kernel source tree, you would type # bzip2 -dc /patch-2660bz2 | patch -p1 -R Backing out of a patch can be risky at times, and it doesn t always work that is, your mileage may vary!

dependence of AGO on T is given by Eq (1313), which may be rewritten:

In this chapter, we discussed the process of configuring and compiling the Linux kernel This isn t exactly a trivial process, but doing it gives you the power to have a fine-grained control of your computer that simply isn t possible with most other operating systems Compiling the kernel is basically a straightforward process The Linux development community has provided excellent tools that make the process as painless as possible In addition to compiling kernels, we walked through the process of upgrading kernels using the patches available from the Linux Kernel web site, wwwkernelorg When you compile a kernel for the first time, do it on a non-production machine, if possible This gives you a chance to take your time and fiddle with the many operational parameters that are available It also means you won t annoy your users if something goes wrong! For programmers curious about the kernel s innards, many references are available in the form of books and web sites, and, of course, the source code itself is the ultimate documentation

Equation (1314) gives the effect of temperature on the equilibrium constant, and hence on the equilibrium conversion If AH" is negative, ie, if the reaction is exothermic, the equilibrium constant decreases as the temperature increases Conversely, K increases with T for an endothermic reaction If A H 0 , the standard enthalpy change (heat) of reaction, is assumed independent of T , integration of Eq (1314) from a particular temperature T' to an arbitrary temperature T leads to the simple result:

12:

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